Temperature stability of ([Na0.5K0.5NbO3]0.93–[LiTaO3]0.07) lead-free piezoelectric ceramics

A polymorphic phase transition (PPT) is often engineered into lead-free materials to generate high piezoelectric activity at room temperature, limiting their temperature stability. We report [Na0.5K0.5NbO3]0.93–[LiTaO3]0.07 tetragonal ceramics with favorable properties over a broad temperature range due to a high Curie temperature at 447 °C and PPT at −15 °C involving a transition to a monoclinic rather than low temperature orthorhombic phase. Piezoelectric k31 and d31 coefficients varied from 0.19 to 0.14 and −53 to −33 pC/N, respectively, over the range of −15 to 300 °C. Strain-electric field loops provided strains of ∼0.2% and a high-field d33 of 205 pm/V.