阳极
阴极
化学
卤化物
电化学
熔盐
无机化学
溴化物
电解质
氯化物
电极
有机化学
物理化学
作者
G. F. Reynolds,Chester J. Dymek
标识
DOI:10.1016/0378-7753(85)80066-5
摘要
Three primary cells (a, b, and c) and two secondary cell candidates (d and e) were examined in room temperature molten salt electrolytes containing either 1-methyl-3-ethylimidazolium chloride (MEICI) (a, b, d, and e), or 1-methyl-3-ethylimidazolium bromide (MEIBr) (c). (a) Al anode/AlCl3-MEICl (N = 0.37)//FeCl3-MEICl (N = 0.33)/W cathode (b) Al anode/AlCl3-MEICl (N = 0.37)//WCl6-MEICl (N = 0.33)/W cathode (c) Al anode/AlBr3-MEIBr (N = 0.33)/Br2/RVC, Pt cathode (d) Zn anode/AlCl3-MEICl (N = 0.33)//AlCl3-MEICl (N = 0.60)/Al cathode (e) Cd anode/AlCl3-MEICl (N = 0.33)//AlCl3-MEICl (N = 0.60)/Al cathode where N is the mole fraction of aluminium halide in the melt. An IONACC® anion exchange membrane separated the anolyte and catholyte solutions in cells (a) and (b), while in cells (d) and (e) a NAFION® cation exchange membrane separated the anolyte and catholyte solutions. In cell (c) a phase boundary separated the anolyte and catholyte solutions, with reticulated vitreous carbon (RVC) acting as the anode current carrier.
科研通智能强力驱动
Strongly Powered by AbleSci AI