蓖麻油
酯交换
环氧化大豆油
甲醇
甲醇钠
催化作用
材料科学
醋酸
过氧化氢
酸值
傅里叶变换红外光谱
有机化学
化学
高分子化学
核化学
化学工程
原材料
工程类
生物化学
作者
G. S. Sudha,Hemjyoti Kalita,Smita Mohanty,SANJAY KUMAR NAYAK
标识
DOI:10.1080/1023666x.2017.1334171
摘要
In the present study, castor oil (CO) was modified by epoxidation, transesterification, and acrylation processes. In situ epoxidation method was used to prepare epoxidized castor oil (ECO) in acetic acid with hydrogen peroxide in the presence of Seralite SRC-120 catalyst. Transesterified epoxidized castor oil was synthesized from the reaction of methanol in the presence of sodium methoxide catalyst. The acrylated epoxidized castor oil was synthesized from the reaction of ECO with acrylic acid containing hydroquinone. Chemical structures of modified CO were analyzed by Fourier transform infrared spectroscopy and proton nuclear magnetic resonance spectra analysis.
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