电解质
容量损失
降级(电信)
淡出
石墨
电化学
锂(药物)
电池(电)
材料科学
分解
电极
泄流深度
化学工程
化学
复合材料
电气工程
热力学
物理化学
有机化学
功率(物理)
内分泌学
工程类
物理
操作系统
医学
计算机科学
作者
Sun Shu,Ting Guan,Bin Shen,Kunyue Leng,Yunzhi Gao,Xinqun Cheng,Geping Yin
标识
DOI:10.1016/j.electacta.2017.03.158
摘要
In this work, the commercial LiFePO4/graphite batteries are cycled under C/3 rate at room temperature (25 °C), 35 °C, 45 °C and 55 °C respectively, and the cycle lifetime is 615 days, 404 days, 159 days and 86 days respectively, which indicates that the capacity fade is strongly dependent upon the ambient temperature. The degradation mechanism of battery capacity is analyzed by the electrochemical and physical characterization. At room temperature, the major reason for the capacity fade of full cells is the irreversible loss of active lithium due to the generation and reformation of SEI film. However, when the ambient temperature exceeds 35 °C, the electrolyte decomposition is greatly enhanced by the elevated temperature which could significantly accelerate and dominate the consumption rate of active lithium. Meanwhile, the elevated temperature has an adverse influence on the performance of LiFePO4 material. In addition, the proportions of effects caused by structure degradation and the surface layer for single electrodes are calculated respectively. Through a series of testing experiments, it is concluded that the degradation mechanism is changed when the test temperature is equal or higher than 45 °C, and the elevated temperature is not a suitable stress factor to accelerate the aging of full cells.
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