Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing

Abstract A novel triazene-anthracene-based fluorescent aminal linked porous organic polymer (TALPOP) was prepared via metal free-Schiff base polycondensation reaction of 9,10-bis-(4,6-diamino- S -triazin-2-yl)anthracene and 2-furaldehyde. The polymer has exceptional chemical and thermal stabilities and exhibit good porosity with Brunauer–Emmett–Teller surface area of 401 m 2 g −1 . The combination of such porosity along with the highly conjugated heteroatom-rich framework enabled the polymer to exhibit exceptional iodine vapor uptake of up to 314 wt % and reversible iodine adsorption in solution. Because of the inclusion of the anthracene moieties, the TALPOP exhibited excellent detection sensitivity towards iodine via florescence quenching with K sv value of 2.9 × 10 3 L mol −1 . The cost effective TALPOP along with its high uptake and sensing of iodine, make it an ideal material for environmental remediation.