光催化
金红石
X射线光电子能谱
锐钛矿
催化作用
材料科学
可见光谱
表面等离子共振
带隙
纳米颗粒
电子顺磁共振
金属
相(物质)
分解水
光化学
兴奋剂
等离子体子
化学工程
纳米技术
化学
核磁共振
光电子学
冶金
生物化学
物理
工程类
有机化学
作者
Mandari Kotesh Kumar,K. Bhavani,Naresh Gutta,B. Srinivas,A. Venugopal
标识
DOI:10.1016/j.apcatb.2016.06.050
摘要
A reaction mechanism has been elucidated on Ag and/or Cu supported on mixed phase (anatase/rutile) of TiO2 and the H2 evolution rates are rationalized by physicochemical characteristics of the fresh and used catalysts by XRD, XPS, TEM and ESR analyses. In situ reduction of Ag-Cu/TiO2 catalyst is monitored by UV-DR spectral studies under natural and artificial light during H2O splitting. The H2-TPR analysis emphasized an interaction between reducible mixed oxides of Ag-Cu particles. Addition of Ag dramatically decreased the band gap of Cu/TiO2 and increased the absorption in the visible light region. The synergism between Ag and Cu nanoparticles generated additional active sites for enhanced H2 yields. A strong interaction between Ag and Cu leads to metal sites (Ag, Cu and/or Ag-Cu) act as electron traps and facilitated electron-hole separation consequently the Ag-Cu/TiO2 sustained longer time.
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