材料科学
电解质
离子电导率
锂(药物)
化学工程
膜
电化学窗口
分离器(采油)
电化学
电极
电导率
物理化学
化学
医学
热力学
物理
工程类
内分泌学
生物化学
作者
Kuirong Deng,Jiaxiang Qin,Shuanjin Wang,Shan Ren,Dongmei Han,Min Xiao,Meng Ye
出处
期刊:Small
[Wiley]
日期:2018-07-03
卷期号:14 (31)
被引量:131
标识
DOI:10.1002/smll.201801420
摘要
Abstract A novel single‐ion conducting polymer electrolyte (SIPE) membrane with high lithium‐ion transference number, good mechanical strength, and excellent ionic conductivity is designed and synthesized by facile coupling of lithium bis(allylmalonato) borate (LiBAMB), pentaerythritol tetrakis (2‐mercaptoacetate) (PETMP) and 3,6‐dioxa‐1,8‐octanedithiol (DODT) in an electrospun poly(vinylidienefluoride) (PVDF) supporting membrane via a one‐step photoinitiated in situ thiol–ene click reaction. The structure‐optimized LiBAMB‐PETMP‐DODT (LPD)@PVDF SIPE shows an outstanding ionic conductivity of 1.32 × 10 −3 S cm −1 at 25 °C, together with a high lithium‐ion transference number of 0.92 and wide electrochemical window up to 6.0 V. The SIPE exhibits high tensile strength of 7.2 MPa and elongation at break of 269%. Due to these superior performances, the SIPE can suppress lithium dendrite growth, which is confirmed by galvanostatic Li plating/stripping cycling test and analysis of morphology of Li metal electrode surface after cycling test. Li|LPD@PVDF|Li symmetric cell maintains an extremely stable and low overpotential without short circuiting over the 1050 h cycle. The Li|LPD@PVDF|LiFePO 4 cell shows excellent rate capacity and outstanding cycle performance compared to cells based on a conventional liquid electrolyte (LE) with Celgard separator. The facile approach of the SIPE provides an effective and promising electrolyte for safe, long‐life, and high‐rate lithium metal batteries.
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