烷基
离子液体
粘度
中间相
剪切减薄
各向同性
热力学
材料科学
牛顿流体
高分子化学
化学
有机化学
复合材料
相(物质)
催化作用
物理
量子力学
作者
Kenneth R. Seddon,Annegret Stark,María-José Torres
出处
期刊:Acs Symposium Series
[American Chemical Society]
日期:2002-05-24
卷期号:: 34-49
被引量:409
标识
DOI:10.1021/bk-2002-0819.ch004
摘要
We report here the viscosity and density of 1-alkyl-3-methylimidazolium salts of [BF4]-, [PF6]-, CL-, [CF3SO3]- and NO3]-.Viscosity decreases as a function of temperature and increases with increasing alkyl chain length, while density decreases with increasing temperature and longer alkyl chain. The viscosity data were fitted to the VFT equation. The ionic liquids were found to exhibit Newtonian behavior when isotropic, whereas they act as non-Newtonian shear-thinning materials at the liquid-crystalline mesophase temperatures.
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