What really controls the atmospheric corrosion of zinc? Effect of marine aerosols on atmospheric corrosion of zinc

腐蚀气溶胶锌溶解沉积（地质）环境化学化学盐（化学）沉积物地质学物理化学古生物学有机化学

作者

Ivan Cole,N.S. Azmat,A.-F. Kanta,Murali Sankar Venkatraman

出处

期刊：International Materials Reviews [Informa]
日期：2009-05-01 卷期号：54 (3): 117-133 被引量：91

标识

摘要

AbstractAbstractThis paper reviews the processes that control the production, transportation and deposition of aerosols and examines how these parameters affect the atmospheric corrosion of zinc on which the aerosols have deposited. The factors that influence the size and chemistry of aerosols are summarised. It is shown that marine aerosols may be acidified through the absorption of gases and strong acids, and that they may attain very low pH values. Aerosol transportation and deposition are size dependent, with aerosol deposition increasing with aerosol size and decreasing with transportation distance. Acidified marine aerosols may be transported to considerable distances from the sources of the acid precursor gases. The review examines the differences in the electrochemical phenomena on zinc surfaces under fine acidified marine or industrial aerosols and under large near neutral aqueous droplets, and shows that the low pH, fine size and high dissolved ionic salt content of the acidified marine aerosols leads to significant oxide dissolution and higher corrosion rates. Acidified marine aerosols disrupt protective oxide films and establish electrochemical cells in which anodic corrosion separation and resistance through the solution are small and oxygen depletion is unlikely. The authors' analysis shows that the susceptibility of zinc to chloride containing environments may in part be associated with the effect of acidified marine aerosols.Keywords: AerosolTransportationDepositionZincCorrosionDropletOxideReview</div> </div> <div class="paper-request-assist"> <div> <a href="/assist/create?paper_id=3QNb6gBlE" class="layui-btn layui-btn-normal"> <span>求助该文献</span> </a> </div> <div class="paper-request-assist-tips"> <div style="color: #f00">最长约 10秒，即可获得该文献文件</div> </div> </div> </div> <div class="paper-sub-wrapper paper-related"> <fieldset class="layui-elem-field layui-field-title" style="text-align: center; "> <legend style="margin-left:0;font-weight:400;">相关文献</legend> </fieldset> <div class="paper-related-content"> <div class="paper-related-content-item" style="text-align: center;position: relative"> <div style="text-align: center"> <img src="https://staticlocesa.ablesci.com/assets/images/ablesci-ai-global-map.jpg" style="width: 60%"> </div> <div 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