化学
磺酸盐
催化作用
共价有机骨架
嘧啶
芳基
共价键
金属有机骨架
硼酸
偶联反应
化学工程
高分子化学
有机化学
立体化学
吸附
钠
烷基
工程类
作者
Quanlu Yang,Ying Zhang,Ning Ding,Qiang Hu,Xiangtao Yan,Jutao Liu,Penghui Zhang,Shuaishuai Fu,Qianshan Wang,Laner Wu,Shang Wu
摘要
Abstract A novel type of porous composites MOF@COF was successfully constructed through decorating covalent organic framework (COF) crystals on the surface of amino‐functionalized metal organic framework (NH 2 ‐MOF). This material has proven to be an excellent catalyst support because it not only overcomes the shortcoming of MOF instability but also combines the advantages of both high specific surface areas. Pd (OAc) 2 is anchored on MOF@COF to obtain MOF@COF‐Pd catalyst. MOF@COF‐Pd is used to catalyze the C–C coupling reaction of pyrimidine sulfonate and aryl boronic acid. The catalyst has the advantages of high stability, catalytic activity, recyclability, and no metal loss. And the application of MOF@COF hybrid materials was expanded in the field of catalysis.
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