阳极
硫黄
钾
碳纤维
热解
化学
化学工程
兴奋剂
石墨
材料科学
电极
有机化学
光电子学
复合数
复合材料
物理化学
工程类
作者
Sun‐Jie Xu,Yu Huang,Wenhong Wei,Fan Ye,Zhi‐Dong Jiang,Renhuan Li,Xing Yuan
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2023-09-04
卷期号:37 (18): 14375-14382
标识
DOI:10.1021/acs.energyfuels.3c02437
摘要
Carbonaceous materials are a class of promising anode candidates for potassium ion batteries, while the practical implementation is handicapped by a limited interlayer, inferior structural stability, and relatively low specific capacity. Herein, scalable sulfur-doped carbon (SCC2) is developed via facile pyrolysis with disposable chopsticks and low-cost sulfur as precursors. Its properties of enlarged interplane distance, increased defect sites, stable hierarchical structure, and uniform sulfur doping bestow it with superior long-term cycling performance of 305.85 mAh g–1 after 2000 cycles at 1.0 A g–1 and excellent rate capability of 210.57 mAh g–1 at a high current density of up to 5.0 A g–1. The excellent performance of SCC2 could be attributed to the appropriate sulfur doping increasing the graphite layer spacing and introducing additional active sites, which are proper for potassium storage.
科研通智能强力驱动
Strongly Powered by AbleSci AI