材料科学
分析化学(期刊)
激发态
兴奋剂
离子
发射光谱
发光
辐射传输
吸收(声学)
激发
光学
原子物理学
谱线
化学
光电子学
物理
天文
量子力学
复合材料
有机化学
色谱法
作者
U. Hömmerich,Samuel Uba,A. Kabir,Sudhir Trivedi,Clayton S.-C. Yang,E. Brown
摘要
We report results of the optical properties of Dy-doped CsPbCl 3 and KPb 2 Cl 5 bulk crystals for potential applications in yellow solid-state laser development. The crystals were synthesized from purified starting materials and melt-grown by vertical Bridgman technique. Optical transmission measurements revealed characteristic absorption bands from intra-4f transitions of Dy 3+ ions. Direct optical excitation at 455 nm ( 6 H 15/2 → 4 I 15/2 ) resulted in dominant yellow emission bands at ∼575 nm from the 4 F 9/2 excited state of Dy 3+ ions. In addition, both crystals exhibited weaker emission lines in the blue (∼483 nm) and red (∼670 nm) regions. The peak emission-cross sections for the yellow transition ( 4 F 9/2 → 6 H 13/2 ) were determined to be ∼0.22 × 10 −20 cm 2 for Dy: CsPbCl 3 (λ peak = 576.5 nm) and ∼0.59 × 10 −20 cm 2 for Dy: KPb 2 Cl 5 (λ peak = 574.5 nm). The spectral properties and decay dynamics of the 4 F 9/2 excited state were evaluated within the Judd-Ofelt theory to predict total radiative decay rates, branching ratios, and emission quantum efficiencies.
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