硅烷
化学
催化作用
联轴节(管道)
有机化学
硅烷
机械工程
工程类
作者
Hui Zhou,Zengbao Yang,Cankun Luo,Jianglian Li,Hai Li,Yong Wu
标识
DOI:10.1002/ejoc.202200961
摘要
Abstract A protocol of Rh(III)‐catalyzed C−H activation utilizing sulfoxonium ylides as traceless directing group and acryloyl silanes has been reported. This strategy provides an efficient and convenient method to construct the tricyclic skeleton of furan‐fused indanone by simultaneously constructing two C−C bonds and one C−O bond in one pot, featuring broad substrate scope. Moreover, the C−H alkenylation have been attained under controlled conditions.
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