材料科学
可穿戴计算机
棱锥(几何)
3d打印
指纹(计算)
可穿戴技术
人工智能
圆锥截面
计算机视觉
指纹识别
模式识别(心理学)
计算机科学
生物医学工程
光学
医学
嵌入式系统
物理
数学
几何学
作者
Dake Huang,Jian Qi,Shuo Gao,Lukui Yin,Houjun Qi,Shuxian Zheng
标识
DOI:10.1021/acsami.5c07889
摘要
Flexible hydrogel sensors have attracted significant attention in wearable applications due to their excellent flexibility and biocompatibility. However, challenges such as insufficient long-term stability, limited sensitivity range, and reliance on traditional molds for microstructure design urgently need to be addressed. This study constructs a dual-ion conductive hydrogel sensor with multilevel conic-pyramid microstructures via Digital Light Processing (DLP) 3D printing, breaking through existing technical bottlenecks. Using an acrylamide (AM)-poly(ethylene glycol) diacrylate (PEGDA) double-network matrix loaded with a Mg2+/Na+ ion system, combined with 30 wt % glycerol modification, the water retention rate of the hydrogel is increased to over 90%, solving the ion concentration fluctuation problem in traditional hydrogels caused by water loss. Simulations comparing six single microstructures show that the conic-pyramid structure, relying on a stepwise compression deformation mechanism (three-level structures sequentially contacting the electrode layer), achieves a sensitivity of 0.544 kPa-1 in the 0-0.8 kPa pressure range, representing a 78% improvement over traditional pyramid structures. It features a response time of 30 ms, a recovery time of 40 ms, and a signal attenuation <4% after 10,000 cycle tests, with stability improved by 56% compared to single Na+ systems. The sensor enables real-time monitoring of finger joint bending (55% resistance variation at 90° bending) and wrist movements (64% resistance variation) through a 9 × 9 orthogonal electrode grid and achieves "handwriting fingerprint" recognition for different writers (signal differences >2.5%) using combined pressure-trajectory features. The high-resolution characteristics (7.8 μm precision, size error <9.13%) of DLP printing breaks through the limitations of traditional molds for complex structures, providing a new paradigm for rapid microstructure prototyping. Compared with existing flexible sensors, this study demonstrates significant improvements in the synergistic performance of sensitivity and stability. The conic-pyramid structure design principle and dual-ion regulation strategy proposed herein offer a universal solution to address sensor performance degradation in complex environments. The "handwriting fingerprint" technology shows broad application potential in identity authentication, medical monitoring, and intelligent anticounterfeiting fields.
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