超级电容器
材料科学
电化学
电容
氢氧化物
化学工程
电解质
镍
基质(水族馆)
堆积
多孔性
电极
功率密度
碳纤维
纳米技术
化学
冶金
复合材料
有机化学
物理化学
海洋学
物理
地质学
工程类
功率(物理)
复合数
量子力学
作者
Haonan Chen,Xiping Lei,Ting Yu,Jing Liu,Kai Fan
出处
期刊:Fuel
[Elsevier]
日期:2022-05-01
卷期号:316: 123357-123357
被引量:4
标识
DOI:10.1016/j.fuel.2022.123357
摘要
Although the capacity of Ni(OH)2 is quite high, the disadvantages such as poor electrical conductivity and severe stacking seriously limit the practical application. Through introduction of turtle shell derived biomass activated carbon (TSHC-5) with hierarchical porous structure as substrate by simple solvothermal method for growth of Ni(OH)2 nanosheets to produce synergistic effect. TSHC-5 provides abundant growth sites for Ni(OH)2, improving interface contact and conductivity. In addition, the 3-D porous structure of TSHC-5 allows for more rapid transport of electrolyte ions, and the stacking during Ni(OH)2 growth is attenuated which exposes more active sites, thus the redox reaction proceeds more rapidly and fully. As a result, the specific capacitance (1752.6F·g−1 at 1 A·g−1) and cycling performance (68.14% after 5000 cycles) of Ni(OH)2/TSHC-5 are demonstrated to be significantly higher compared to that of Ni(OH)2. Moreover, the asymmetric supercapacitor assembled with Ni(OH)2/TSHC-5 achieves an energy density of 58.18 Wh·kg−1 at a power density of 800 W·kg−1, which maintains excellent cycling performance with 74.52% initial specific capacitance retention after 5000 cycles. The excellent electrochemical performance based on Ni(OH)2/TSHC-5 as electrode material allows a broad application in energy storage and energy conversion.
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