X射线光电子能谱
材料科学
涂层
电化学
循环伏安法
阴极
电解质
锂(药物)
兴奋剂
化学工程
分析化学(期刊)
电极
复合材料
化学
色谱法
工程类
内分泌学
物理化学
医学
光电子学
作者
Tahir Sattar,Seong-Ju Sim,Seung Hwan Lee,Bong‐Soo Jin,Hyunsoo Kim
标识
DOI:10.1016/j.ssi.2022.115886
摘要
The LiNi0.91Co0.06Mn0.03O2 Ni-rich cathode material is modified with Mg doping and Li3PO4 coating through an efficient and single-step method. The samples are characterized by XPS, XRD, FESEM and FETEM. Cycling results demonstrate that, 1 mol% MgHPO4 modified NCM (MgP-1) exhibits 73.5% capacity retention while pristine sample shows only 50.6% at 4.3 V cycling. The presence of Mg2+ inside the crystal lattice provides pillaring effect during delithiation which screen O2− — O2− repulsion that inhibits the phase transition in the modified samples. These results are confirmed by cyclic voltammetry test. Besides that, transforming the surface residual lithium into lithium phosphate (Li3PO4) coating on the active material surface is facilitating the Li+ diffusion during cycling. In addition, this coating acted as a protective layer against hostile attack of electrolyte. The lower Rct of MgP-1 is due to the Li3PO4 coating which contributes to the highest discharge capacity at high current rate (160.8 mAh g−1 at 2C and 124.6 mAh g−1 3C) as compared to pristine (157.2 mAh g−1 at 2C and 107.2 mAh g−1 at 3C). These results confirm that Mg doping along with Li-ion conductor Li3PO4 coating is a promising technique to control the surface residual lithium and enhance the electrochemical performance of cathode electrode.
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