光催化
结晶度
材料科学
半导体
价(化学)
催化作用
选择性
分子
兴奋剂
纳米技术
溶剂
化学工程
化学
光电子学
有机化学
工程类
复合材料
作者
Francesco Parrino,Leonardo Palmisano,Elisa I. García‐López,Giuseppe Marcı̀,Vittorio Loddo
出处
期刊:ACS Catalysis
日期:2018-10-19
卷期号:8 (12): 11191-11225
被引量:173
标识
DOI:10.1021/acscatal.8b03093
摘要
This article reviews the parameters that influence heterogeneous photocatalysis (PC) for selective synthesis of high value chemicals alone or coupled with other technologies.In particular, the parameters related to the photocatalysts as crystallinity degree, type of polymorph, surface acid-base properties, exposure of particular crystalline facets, coupling of different semiconductors, position of the valence and conduction band edge, addition of doping agents, and those related to the reaction system as setup configuration and reactor geometry, type of solvent, type and amount of photocatalyst, affecting the selectivity towards specific products, are described and discussed.The presented results highlight that a precise evaluation of the efficiency of the process is a challenging but necessary task to be approached in order to allow real applications of photocatalytic processes.
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