微型多孔材料
吸附
化学工程
共晶体系
烟气
材料科学
碳纤维
盐(化学)
活性炭
催化作用
选择性吸附
化学
有机化学
微观结构
复合材料
工程类
复合数
作者
Shasha Wang,Yuelong Xu,Junfeng Miao,Mengshuai Liu,Bin Ren,Lihui Zhang,Zhenfa Liu
标识
DOI:10.1016/j.jclepro.2020.120023
摘要
Microporous carbon xerogels (CXs) were successfully fabricated via a facile one-pot strategy using eutectic salt mixture (KCl and ZnCl2) as dual activator and catalyst. Their pore structures, morphology, and selective CO2 adsorption behaviors were thoroughly studied by varying the contents of eutectic salt mixture. The presented CXs herein showed excellent CO2 adsorption selectivities, and the CX-4 with optimum salt concentration (12.9%) exhibited the highest CO2 adsorption capacity of 4.39 mmol g−1 at 273 K, which was ascribed to their special microscopic pore structure. Compared with the reported carbon materials, the optimum CX-4 exhibits a comparable or superior CO2 adsorption performance under similar conditions, showing great potential for efficient CO2 capture and separation from flue gas and natural gas.
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