杀虫剂
百草枯
农药残留
表面增强拉曼光谱
拉曼光谱
化学
检出限
试剂
环境化学
纳米技术
分析化学(期刊)
色谱法
材料科学
有机化学
拉曼散射
生物
光学
物理
农学
作者
Wan-Ling Chen,Feng Long,Guofen Song,Jing Chen,Shuai Peng,Penghui Li
摘要
Abstract Pesticide residues are one of the major food safety concerns for consumers all over the world, and it is crucial to develop simple, rapid, and effective method for the detection of pesticide residues. In the study, we report the sensitive detection of pesticides with the dynamic surface‐enhanced Raman spectroscopy (dynamic SERS) method. The dynamic SERS method provides excellent detection sensitivity at the metastable state of plasmonic nanoparticles in the sessile drop, which is a critical state between the wet state and dry state during the volatilization process. With this simple and rapid method, the SERS performance towards four pesticides, paraquat, thiabendazole, tricyclazole, and isocarbophos, is investigated with silver nanoparticles (AgNPs) as the enhancing reagents. The characteristic SERS spectra of paraquat, thiabendazole, tricyclazole, and isocarbophos can be detected at concentrations down to 1 × 10 −9 M, 5 × 10 −9 M, 5.28 × 10 −9 M, and 3.45 × 10 −7 M, respectively. The pesticides are also discriminable at the same concentrations as the standard solution counterparts from the pesticides spiked vegetable extracts, and linear relationship can be drawn from the characteristic peak intensities and negative logarithm of concentrations of the four pesticides. Therefore, the simple and rapid dynamic SERS method shows great potential in the practical detection of pesticide residues.
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