化学
电解
电极
循环伏安法
电化学
电解质
阴极保护
阳极
串扰
动能
分析化学(期刊)
标准电极电位
无机化学
物理化学
电子工程
有机化学
工程类
物理
量子力学
作者
Kingo Ariyoshi,Atsushi Maekawa,Taichi Nakamura
标识
DOI:10.1016/j.jelechem.2022.116383
摘要
Crosstalk reactions in Li-ion batteries play an important role in the capacity fading caused by imbalance of the states-of-charge between positive and negative electrodes. A quantitative understanding of these reactions can enable estimation of battery life. Because crosstalk reactions are complex phenomena in which chemical species produced by a side reaction at one electrode react at the other electrode, a generator–collector-type electrochemical cell is required to investigate these reactions. Therefore, a new four-electrode cell was constructed in this study, in which oxidative decomposition of an electrolyte was achieved by constant-current electrolysis at one Al2O3 electrode, and the reduction of the generated oxidants was detected by cyclic voltammetry (CV) at the other Al2O3 electrode. CV indicated that the cathodic current due to the crosstalk reaction increased during electrolysis, and that two cathodic peaks appeared at 1.3 and 1.8 V. The cathodic current eventually stabilized and decreased to zero after electrolysis. A kinetic equation that expressed the crosstalk-reaction-induced cathodic current provided a decent fit to the observed current via kinetic parameters. This kinetic equation is remarkably useful for quantitatively understanding the electrochemical nature of crosstalk reactions and can help predict the side-reaction currents in actual batteries through the derived kinetic parameters, which can determine battery life.
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