析氧
电催化剂
材料科学
电解
分解水
过电位
电化学
贵金属
碳纤维
电解水
镍
催化作用
化学工程
化学
无机化学
电极
复合数
金属
冶金
物理化学
光催化
复合材料
有机化学
电解质
工程类
作者
Zhiyuan Liu,Yongju He,Cuimei Yao,Xiaoyu Ji,Bin Zhao,Dejian Gao,Payam Ahmadian Koudakan
标识
DOI:10.1016/j.jpcs.2022.110602
摘要
Searching for efficient, high active, and low-cost electrocatalysts toward oxygen evolution reaction (OER) is of immense importance in commercial water electrolysis application. In view of this, a novel approach is applied to design a self-supported Cu–Ni–Se nanostuctures on carbon cloth (CC) derived from Cu–Ni-MOF nanorectangles for OER (Cu–Ni–[email protected]). The self-supported Cu–Ni–[email protected] renders an overpotential as low as 270 mV at the current density of 10 mA cm−2 for OER in KOH (1 M) alkaline solution with high stability. The outstanding OER electrocatalytic activity of Cu–Ni–[email protected] can be originated from its unique properties such as high active sites exposure, high surface areas, and effective mass transport channels. This work provides new insights for the rational engineering of advanced composite nanostructures based on noble-metal-free OER electrocatalyst with high efficient and low-cost features.
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