光致发光
煅烧
材料科学
X射线光电子能谱
傅里叶变换红外光谱
介孔材料
纳米颗粒
化学工程
热重分析
介孔二氧化硅
光谱学
纳米技术
化学
有机化学
催化作用
光电子学
工程类
物理
量子力学
作者
Shadmani Shamim,Gabriel L. Hornyak,Daniel Crespy,Htet Htet Kyaw,Tanujjal Bora
标识
DOI:10.1016/j.materresbull.2022.111842
摘要
Synthesis of dye-free mesoporous silica nanoparticles and the effect of calcination on their photoluminescence properties are reported here. Mesoporous silica nanoparticles were synthesized using a modified Stöber method and calcined at different temperatures. Samples were characterized by transmission electron microscopy (TEM), BET surface area analyzer, thermogravimetry analyzer, Fourier Transform Infrared spectroscopy (FTIR), photoluminescence spectroscopy, and X-ray photoelectron spectroscopy (XPS). Silica nanoparticles calcined at 400 °C exhibited maximum porosity with highest specific surface area of 828 m2.g–1. Uncalcined porous nanoparticles exhibit broad visible light photoluminescence (from 400 nm to 600 nm), and its intensity varies significantly after calcination, mainly due to the creation of carbon impurities and oxygen defects within the silica lattice. Carbon impurities during calcination are formed from the remaining organic residue at the nanoparticle's surface and can be removed by calcining the particles above 400 °C and thereby, improving the visible light photoluminescence intensity of these nanoparticles.
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