催化作用
材料科学
电化学
动力学
锂(药物)
化学工程
电催化剂
阴极
氧化还原
吸附
硫黄
储能
纳米技术
电极
物理化学
化学
热力学
有机化学
内分泌学
量子力学
工程类
物理
功率(物理)
冶金
医学
作者
Xu Zhou,Tingting Liu,Genfu Zhao,Xiaofei Yang,Hong Guo
标识
DOI:10.1016/j.ensm.2021.05.009
摘要
The high theoretical energy density and low cost make lithium-sulfur (Li-S) batteries an ideal choice for next-generation energy storage devices. However, the slow kinetics cause the reaction process to be incomplete and low reaction rate. To solve this problem, a novel cooperative catalytic interface with fine molecular regulation mechanism is designed by taking advantage of the electronic correlation between the catalyst and polysulfides (LiPSs), which multi-step process contains chemical adsorption, catalytic activity center and lithium-ion transfer. The cooperative catalytic interface greatly accelerates the kinetics of LiPSs conversion, precipitation of Li2S in discharging, and insoluble Li2S decomposition in charging process. Therefore, the [email protected]3N4-based cathode exhibits an outstanding electrochemical performance. Even under the condition of high sulfur loading of 6.0 mg cm−2, the constructed Li-S batteries demonstrate the ultralow capacity decay rate of 0.025% per cycle up to 1000 cycles. Moreover, its catalytic mechanism is deeply analyzed through DFT theory and in(ex)-situ technologies. This work will open a new window for the rational design of Li-S electrocatalyst based on cooperative interface.
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