结晶
材料科学
Crystal(编程语言)
氢键
化学工程
分子
聚对苯二甲酸乙二醇酯
结晶习性
高分子化学
结晶学
复合材料
化学
有机化学
计算机科学
工程类
程序设计语言
作者
Peiquan Yuan,Bao‐Shu Liu,Hua Sun
标识
DOI:10.1002/crat.202100025
摘要
Abstract The crystallization process of bis(2‐hydroxyethyl) terephthalate is experimentally investigated. The optimized crystals of bis(2‐hydroxyethyl) terephthalate have the median particle size ( D 50 ) of 1300 µm and a perfect crystal habit, and their diameter span reduces from 11.48 (before optimization) to 1.72 (after optimization). The results show that more oxygen atoms at both ends of the crystal are exposed to the crystal surfaces, which make it easy to form hydrogen bonds with free bis(2‐hydroxyethyl) terephthalate. Therefore, the crystal surfaces at both ends grow fastest and tend to disappear eventually.
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