四溴双酚A
催化作用
化学
傅里叶变换红外光谱
煅烧
X射线光电子能谱
拉曼光谱
激进的
硫酸盐
无机化学
核化学
降级(电信)
纳米颗粒
化学工程
材料科学
有机化学
纳米技术
阻燃剂
电信
物理
光学
计算机科学
工程类
作者
Yusong Ding,Lihua Zhu,Nan Wang,Heqing Tang
标识
DOI:10.1016/j.apcatb.2012.09.015
摘要
CuFe2O4 magnetic nanoparticles (MNPs) were prepared by sol–gel combustion method with copper and iron nitrates as metal precursors and citrate acid as a complex agent. The obtained CuFe2O4 MNPs were characterized by scanning electron microscopy, X-ray diffractometry, Fourier transform infrared spectroscopy, Fourier transform Raman spectroscopy and X-ray photoelectron spectroscopy. It was found that CuFe2O4 MNPs could effectively catalyze peroxymonosulfate (PMS) to generate sulfate radicals (SO4−) to degrade tetrabromobisphenol A (TBBPA). The added TBBPA (10 mg L−1) was almost completely removed (with a removal of 99%) in 30 min by using 0.1 g L−1 CuFe2O4 MNPs and 0.2 mmol L−1 PMS. With higher addition of PMS (1.5 mmol L−1), the degradation yielded a TOC removal of 56% and a TBBPA debromination ratio of 67%. The effect of catalyst calcination temperature, catalyst load, PMS concentration and reaction temperature was investigated on the catalytic activity of CuFe2O4 MNPs. The highly catalytic activity of CuFe2O4 MNPs possibly involved the activation of PMS by both Cu(II) and Fe(III) in CuFe2O4 MNPs. Based on intermediate detections, the degradation pathway of TBBPA in the CuFe2O4 MNPs/PMS system was proposed.
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