化学
粒径
聚合物
螯合作用
配位聚合物
合理设计
粒子(生态学)
航程(航空)
协调数
纳米技术
高分子化学
化学工程
结晶学
无机化学
物理化学
有机化学
离子
复合材料
材料科学
工程类
地质学
海洋学
作者
Yadong Chiang,Ming Hu,Yuichiro Kamachi,Shinsuke Ishihara,Kimiko Takai,Yoshihiro Tsujimoto,Katsuhiko Ariga,Kevin C.‐W. Wu,Yusuke Yamauchi
标识
DOI:10.1002/ejic.201300112
摘要
Abstract We demonstrate that the particle sizes in cyano‐bridged coordination polymers consisting of Ni II –C≡N–Fe II units are precisely controlled by changing the amount of chelating agent, sodium citrate. With an increase in the amount of chelating agent added, the average size of the particles gradually increases from 20 to 350 nm with retention of a well‐defined cubic shape. Furthermore, the use of different Fe sources expands the possible control range up to 500 nm.
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