Visible light decomposition of ammonia to dinitrogen by a new visible light photocatalytic system composed of sensitizer (Ru(bpy)32+), electron mediator (methylviologen) and electron acceptor (dioxygen)

Visible light decomposition of aqueous ammonia to dinitrogen was successfully achieved by using a new photocatalytic system based on a molecular photoelectron relay composed of a sensitizer (Ru(bpy)(3)2+), an electron mediator (methylviologen) and an electron acceptor (dioxygen), which can be used as a visible light-driven photocatalyst instead of UV-driven semiconductors.