石墨烯
阳极
材料科学
锂(药物)
多孔性
纳米孔
纳米技术
微观结构
化学工程
电池(电)
石墨烯泡沫
储能
锂离子电池
电极
复合材料
氧化石墨烯纸
化学
内分泌学
物理化学
功率(物理)
工程类
物理
医学
量子力学
作者
Baolin Xing,Huihui Zeng,Guangxu Huang,Chuanxiang Zhang,Ruifu Yuan,Yijun Cao,Zhengfei Chen,Jianglong Yu
标识
DOI:10.1016/j.jallcom.2018.11.288
摘要
Porous graphene has attracted considerable attention for its promising potential application in energy storage devices due to its unique porous structure combined with inherent electronic characteristics of graphene. Herein, a cost effective and environmentally friendly strategy is developed to prepare porous graphene via graphitization coupled with liquid oxidation-rapid thermal reduction using anthracite as a precursor. The prepared porous graphene has microstructure features such as highly continuous corrugated nanosheets with micro-meso-macro hierarchical porous structure, high specific surface area (640 m2 g−1) and large pore volume (3.792 cm3 g−1) with large amount of structural defects and nanopores, which provides sufficient active sites for lithium ions storage and offers favorable pathways for the fast transportation of lithium ions and electrons. When used as anode materials for lithium-ion batteries, such porous graphene exhibits a high reversible capacity of 770 mAh·g−1 at current density of 0.1 C, and possesses an outstanding rate capability with desirable capacities of 274 mAh·g−1 and 224 mAh·g−1 even at high current densities of 10 C and 20 C. Moreover, such porous graphene also demonstrates superior cycling performance up to 98.0% of the initial reversible capacity retention after 110 cycles. This study paves a promising approach to the large-scale production of porous graphene from coal for high performance anode materials used in lithium-ion batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI