Low-peroxide-consumption Fenton-like Systems: The future of advanced oxidation processes

Conventional heterogeneous Fenton-like systems employing different peroxides have been developed for water/wastewater remediation. However, a large population of peroxides consumed during various Fenton-like systems with low utilization efficiency and associated secondary contamination have become the bottlenecks for their actual applications. Recent strategies for lowering the peroxide consumptions to develop economic Fenton-like systems are primarily devoted to the effective radical generation and subsequent high-efficiency radical utilization through catalysts/systems engineering, leveraging emerging nonradical oxidation pathways with higher selectivity and longer life of the reactive intermediate, as well as reactor designs for promoting the mass transfer and peroxides decomposition to improve the yield of radicals/nonradicals. However, a comparative review summarizing the mechanisms and pathways of these strategies has not yet been published. In this review, we endeavor to showcase the designated systems achieving the reduction of peroxides while ensuring high catalytic activity from the perspective of the above strategic mechanisms. An in-depth understanding of these aspects will help elucidate the key mechanisms for achieving economic peroxide consumption. Finally, the existing problems of these strategies are put forward, and new ideas and research directions for lowering peroxide consumption are proposed to promote the application of various Fenton-like systems in actual wastewater purification.