Silver‐Catalyzed Decarboxylative Acylfluorination of Two Alkenes with Ketonic Acids

Abstract An acylative fluorination of two different alkenes is developed, assisted by the interaction of silver catalyst and Selectflour. Various α‐ketonic acids can be decarboxylated to form acyl radicals at 35 °C, sequentially add to the electron‐deficient and electron‐ rich alkenes to provide the benzyl fluorinated compounds containing diversified functional groups.