材料科学
正交晶系
电介质
结构精修
相变
铁电性
反铁电性
掺杂剂
陶瓷
相(物质)
化学计量学
大气温度范围
分析化学(期刊)
兴奋剂
晶体结构
凝聚态物理
结晶学
光电子学
物理化学
热力学
复合材料
化学
有机化学
物理
作者
Jiayi He,Xiao Liu,Min Li,Zhiyun Zhang,Li Zhang,Tao Zhang,Huiling Du,Jing Shi
标识
DOI:10.1016/j.ceramint.2022.07.212
摘要
Systematic investigation on the phase transition, dielectric behavior, and ferroelectric property of non-stoichiometric sodium niobate-based antiferroelectric (AFE) ceramics is carried out via Bi-substitution. Doping Bi3+ is capable of adjusting phase transition temperature meanwhile accelerating the formation of polar nanoregions instead of the long-range order structure. The phase transition is identified by the structural Rietveld refinement from the orthorhombic P phase to the pseudo-cubic phase consisting of the P and orthorhombic R phase as Bi3+ dopant increases. The composition regulation shifts the dielectric anomaly to a lower temperature and effectively enhances the relaxor nature. Specifically, associated with the diffuse dielectric relaxation aroused by oxygen vacancy defect, excellent thermal stability is achieved in a wide temperature range from −82 °C to 408 °C. Additionally, the simultaneously significant improvement of the recoverable energy density and efficiency is gained at moderate electric fields. This work makes it an alternative AFE strategy for the application of high-temperature capacitor.
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