化学
酮
分子氧
催化作用
功能群
钴
酒
二醇
氧气
有机化学
组合化学
聚合物
作者
Xiaosong Hao,Huihui Ji,Hongbing Zhan,Qian Zhang,Dong Li
标识
DOI:10.1002/adsc.202100921
摘要
Abstract A cobalt‐catalyzed selective dioxygenation of styrenes with N ‐hydroxyphthalimide (NHPI) was developed using molecular oxygen as the terminal oxidant. Alcohol and ketone products can be selectively formed from identical substrates by catalyst control. The reaction was applicable to a broad range of styrenes and exhibited good functional group tolerance. It provided a method for preparation of 1,2‐diol or α‐hydroxyketone derivatives. magnified image
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