Lignin reinforced hydrogels with multi-functional sensing and moist-electric generating applications

Hydrogels, including PVA hydrogels, have numerous applications in many fields; however, their poor mechanical strength limits their utilization potential. Lignin, the most abundant aromatic biopolymer in nature from lignocellulosic biomass, is presently under-utilized. Herein, we used lignin to improve strength and impart pH-responsive properties of PVA hydrogel. The lignin reinforced PVA (LRP) hydrogel has a maximum storage modulus of 83.1 kPa, which is much higher than the PVA hydrogel. The LRP hydrogel exhibits great ionic conductivity, mechanical properties, and strain-sensitivity even at -30 °C. The LRP hydrogel is subsequently applied for a moisture-induced electric generator, which delivers a voltage output of 226.6 mV from moisture flow. The eco-friendly, pH responsive, high antifreezing, ionic conductive, strain sensitive, and moist-electric generating hydrogels have potential applications in many fields, including biomedicine, flexible electrodes, pH-responsive switch, strain sensor, and next-generation self-powered device systems.