甲基异丁基酮
离子强度
化学
铜
萃取(化学)
磷酸
酮
双水相体系
高氯酸盐
无机化学
化学计量学
离子液体
水溶液
核化学
有机化学
催化作用
离子
作者
Sihem Djebabra,Hanane Rehali,Wafa Mimi
标识
DOI:10.1002/slct.202203045
摘要
Abstract This work concerns the study of the extraction of copper (II) in the perchlorate medium by Bis‐2‐ethylhexyl phosphoric acid (D2EHPA) in methyl isobutyl ketone (MIBK) at 25 °C at different ionic strength (1, 1/6, 1/10 mol kg −1 ). The stoichiometry of the reaction of extracted complexations was determined by the slope method. The organometallic complexes extracted in the organic phase are of the type CuL 2 in methyl isobutyl ketone has unit ionic strength. The organometallic complexes extracted in the organic phase are of the type CuL 2 ClO 4 (H 2 O) or CuL 2 ClO 4 (MIBK)x in methyl isobutyl ketone has different ionic strength Efficiency of the extraction of copper (II) depends on the ionic strength of the aqueous medium. Hence when the ionic strength of the aqueous perchlorate medium increases the extraction of copper (II) increases.
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