硝化作用
光催化
化学
光化学
区域选择性
苯酚
苯并咪唑
亲核细胞
硝基
催化作用
有机化学
烷基
作者
Dong Liang,Xiaoyu Zhang,Yanle Li,Yumiao Zhou,Mengyu Ren,Xiaoyue Zhang,Yongxiang Li,Na Zhu
标识
DOI:10.1016/j.scp.2023.101077
摘要
An energy-saving and friendly process was performed on the Ag/g-C3N4 photocatalyst to achieve the halo-nitro-phenol intermediates with the ipso-nitration of bromophenols and nitrite. As detected by SEM, TEM and XRD, Ag nanoparticles are proved to be located on the surface of g-C3N4 and lead to the improvement of photocatalytic ability by UV–vis, PL spectra and photoelectronic analysis. The substituents of bromophenols could be immediately related to their regioselective conversion. The fluoro-, chloro-, and bromo-substituted bromophenols revealed the higher nucleophilic potential than the alkyl- and alkoxyl-substituted ones. From the inhibition experiment and EPR analysis, the photo-generated superoxide and active holes played crucial roles in photocatalytic nitration through the peroxynitrite way into ·NO2 radicals. Finally, the electrostatic potentials of all bromophenols were calculated on Gaussian09 W software to explain the distribution of photo-driven nitration products.
科研通智能强力驱动
Strongly Powered by AbleSci AI