Effect of three penicillin-based as corrosion inhibitors on Q235 steel in hydrochloric acid

腐蚀 盐酸 化学 吸附 金属 阴极保护 朗缪尔吸附模型 核化学 无机化学 阳极 有机化学 电极 物理化学
作者
Feng Li,Hailing Yao,Xuemei Ma,Hailin Zhu,Zhiyong Hu
出处
期刊:International Journal of Electrochemical Science [Elsevier BV]
卷期号:18 (12): 100368-100368 被引量:7
标识
DOI:10.1016/j.ijoes.2023.100368
摘要

This study investigated the effects of three penicillin-based inhibitors (carbenicillin sodium (CS), ampicillin sodium (AS), and sulbenicillin sodium (SS)) on corrosion inhibition for Q235 steel in 1 M hydrochloric acid solution. The findings revealed that all three inhibitors demonstrated remarkable effectiveness in inhibiting corrosion. Furthermore, the study established a clear correlation between the concentration of these inhibitors and their corrosion inhibition capabilities, indicating that higher concentrations led to enhanced inhibition. Conversely, as the temperature increased, the corrosion inhibition performance of the inhibitors decreased. The most substantial corrosion inhibition efficiencies were achieved at an optimal concentration of 8 mM, with CS reaching 96.82%, AS achieving 96.32%, and SS attaining 94.28% efficiency, respectively. Additionally, the study identified a mixed-type corrosion inhibition mechanism employed by these inhibitors, indicating their involvement in both anodic and cathodic corrosion processes. Moreover, the inhibitors adhered to the Langmuir adsorption isotherm when interacting with the metal surface.

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