化学
区域选择性
催化作用
戒指（化学）
键裂
脂质过氧化
锰
劈理（地质）
有机化学
组合化学
立体化学
抗氧化剂
断裂（地质）
工程类
岩土工程
作者
Chenhao Lou,Leiyang Lv,Zhiping Li
标识
DOI：10.1002/adsc.202200705
摘要
Abstract A manganese‐catalyzed regioselective ring‐opening peroxidation of cyclobutanols has been disclosed. With this protocol, the C( sp 3 )−OOBu‐ t bond could be efficiently constructed via the radical‐mediated C−C bond cleavage/coupling, allowing the facile access to a variety of 4‐oxo peroxides. Besides, the obtained peroxidation products could be readily transformed into other synthetically attractive skeletons. magnified image
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