Charge Accumulation Effect Enabled by a Bioinspired Self‐lubricating Triboelectric Nanogenerator for Both High Average Power Density and Long Durability

Abstract Recently through the synergetic utilization of triboelectrification, electrostatic induction, and electrostatic discharge, a novel dual‐functional triboelectric nanogenerator (DF‐TENG) has been developed, which can not only generate a motion‐responsible alternating current/ direct current output but also provide a higher performance compared to traditional TENGs. However, further improvements in performance and lifespan are crucial and remain challenging for the future large‐scale application of this new‐type TENG. Herein, a novel bioinspired self‐lubricating prototype is presented (BS‐TENG), which employs a porous polyurethane (PU) matrix impregnated with a low‐viscosity dielectric lubricant. In response to external mechanical stimuli, the BS‐TENG can “secrete” pre‐stored lubricant to partially fill micro‐gaps between tribo‐layers, thus forming self‐lubrication. This self‐lubricating mechanism not only elevates the electrostatic discharge threshold between tribo‐layers to maximize charge accumulation, thereby facilitating efficient energy release through electrostatic discharge for enhanced power output, but also significantly reduces material abrasion and realizes superior output durability. Benefiting from this effect, the BS‐TENG delivers an average power density of up to 4.6 W m −2 , with extraordinary stability to retain 99% of its initial output even after over 60 000 cycles. This work provides a straightforward and effective strategy for realizing high‐performance and long‐stability TENGs, paving the way for their practical applications.