石墨氮化碳
光催化
氧气
材料科学
氮化碳
析氧
碳纤维
化学工程
氮气
氮化物
多孔性
胶体
光电效应
光化学
纳米技术
化学
催化作用
有机化学
复合材料
图层(电子)
光电子学
物理化学
工程类
复合数
电化学
电极
作者
Xiangjie Yang,Xiangbin Yu,Xiangjie Yang,Xinzhe Wang,Jiaming Yang,Xuyang Huo,Qiuju Qi
出处
期刊:RSC Advances
[The Royal Society of Chemistry]
日期:2022-01-01
卷期号:12 (52): 33688-33695
被引量:1
摘要
Porous structure design and the content regulation of heteroelements have been proved to be effective strategies to boost photocatalytic H2 generation activity of graphitic carbon nitride (g-C3N4) based photocatalyst. Herein, a series of porous graphitic carbon nitride with high concentration of oxygen (g-C3N4-O) photocatalysts were synthesized via in situ polymerization process using colloidal SiO2 as oxygen source. The content of oxygen within the g-C3N4-O photocatalysts could be tuned by adjusting the amount of added colloidal SiO2 during the preparation procedure. The introduced oxygen replaced two-coordinated nitrogen atom, influencing band edge position and localized electron distribution, thereby enhancing visible light harvesting and photoelectric conversion. As a result, the g-C3N4-O photocatalyst with an optimal oxygen content (8.39 wt%) showed 10.5 fold enhancement in H2 evolution rate compared to that of bulk g-C3N4, attributed to the porous structure and high concentration of incorporated oxygen.
科研通智能强力驱动
Strongly Powered by AbleSci AI