催化作用
化学
脱氢
氢
电化学
无机化学
化学工程
物理化学
电极
生物化学
工程类
有机化学
作者
Tonghui Zhao,Mengting Li,Dongdong Xiao,Xiaoju Yang,Liwei An,Zhongmin Deng,Tao Shen,Mingxing Gong,Yi Chen,Hongfang Liu,Ligang Feng,Xuan Yang,Li Li,Deli Wang
标识
DOI:10.1002/ange.202315148
摘要
Abstract Tracking the trajectory of hydrogen intermediates during hydrogen electro‐catalysis is beneficial for designing synergetic multi‐component catalysts with division of chemical labor. Herein, we demonstrate a novel dynamic lattice hydrogen (LH) migration mechanism that leads to two orders of magnitude increase in the alkaline hydrogen oxidation reaction (HOR) activity on Pd@Pt over pure Pd, even ≈31.8 times mass activity enhancement than commercial Pt. Specifically, the polarization‐driven electrochemical hydrogenation process from Pd@Pt to PdH x @Pt by incorporating LH allows more surface vacancy Pt sites to increase the surface H coverage. The inverse dehydrogenation process makes PdH x as an H reservoir, providing LH migrates to the surface of Pt and participates in the HOR. Meanwhile, the formation of PdH x induces electronic effect, lowering the energy barrier of rate‐determining Volmer step, thus resulting in the HOR kinetics on Pd@Pt being proportional to the LH concentration in the in situ formed PdH x @Pt. Moreover, this dynamic catalysis mechanism would open up the catalysts scope for hydrogen electro‐catalysis.
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