高价分子
化学
酚类
试剂
碘
有机化学
组合化学
苯酚
作者
Hanliang Zheng,Xiao‐Song Xue
标识
DOI:10.2174/1385272824999200620223218
摘要
Hypervalent iodine-promoted dearomatization of phenols has received intense attention. This mini-review summarizes recent computational mechanistic studies of phenolic dearomatizations promoted by hypervalent iodine(III) reagents or catalysts. The first part of this review describes mechanisms of racemic dearomatization of phenols, paying special attention to the associative and dissociative pathways. The second part focuses on mechanisms and selectivities of diastereo- or enantio-selective dearomatization of phenols.
科研通智能强力驱动
Strongly Powered by AbleSci AI