Two-Dimensional Imprinting Strategy to Create Specific Nanotrap for Selective Uranium Adsorption with Ultrahigh Capacity

Uranium extraction is highly challenging because of low uranium concentration, high salinity, and a large number of competing ions in different environments. The template strategy is developed to address the defect of poor selectivity, but the adsorption capacity is limited by cavity blocking during the preparation of materials. Herein, a two-dimensional (2D) imprinting strategy is adopted to design 2D imprinted networks with specific nanotraps for effective uranium capture. The imprinted networks are established through the condensation polymerization of uranyl complexes, which are formed by aromatic building units coordinating with uranyl ions on the equatorial plane. Different from traditional imprinting materials that contain many invalid cavities (buried cavities or unreleased cavities), the as-prepared adsorbents possess tailored 2D nanotraps, which are open and specific to uranyl. Thus, the optimized networks not only show excellent selectivity for uranium (K_d = 964,500 mL/g in multi-ion solution) and slight disturbance of high salinity but also possess an ultrahigh adsorption capacity of 1365.7 mg/g. In addition, this adsorbent shows a high extraction efficiency for uranium under a wide range of pH conditions and exhibits good regeneration performance. This work proposes a pioneering strategy of 2D imprinting networks to capture uranium specifically with high capacity and can be applied to material design in many other fields.