Chiral TADF‐Active Polymers for High‐Efficiency Circularly Polarized Organic Light‐Emitting Diodes

Abstract A strategy of chiral donor–acceptor copolymerization is proposed to develop chiral nonconjugated polymers with thermally activated delayed fluorescence (TADF). Based on this strategy, two pairs of chiral polymers ( R , R )‐/( S , S )‐ pTpAcDPS and ( R , R )‐/( S , S )‐ pTpAcBP were synthesized. The alternating copolymerization of the chiral donors and acceptors could effectively separate the frontier molecular orbitals, which made the polymers show small Δ E ST of 0.01–0.03 eV and efficient TADF properties. Moreover, the polymers also showed the quantum yield of up to 92 % and the circularly polarized luminescence. The solution‐processed circularly polarized organic light‐emitting diodes showed circularly polarized electroluminescence signals with high external quantum efficiencies of up to 22.1 % and maximum luminance of up to 34350 cd m −2 . This is the first report of CP‐OLEDs based on chiral TADF polymer, which provides a useful and valuable guidance for the development of high‐efficiency CPEL polymers.