解聚
木质素
催化作用
生物高聚物
化学
生化工程
绿色化学
产量(工程)
有机化学
生物技术
纳米技术
反应机理
材料科学
聚合物
生物
工程类
冶金
作者
Christoph A. Gasser,Gregor Hommes,Andreas Schäffer,Philippe F.-X. Corvini
标识
DOI:10.1007/s00253-012-4178-x
摘要
Considerable effort has been dedicated to the chemical depolymerization of lignin, a biopolymer constituting a possible renewable source for aromatic value-added chemicals. However, these efforts yielded limited success up until now. Efficient lignin conversion might necessitate novel catalysts enabling new types of reactions. The use of multiple catalysts, including a combination of biocatalysts, might be necessary. New perspectives for the combination of bio- and inorganic catalysts in one-pot reactions are emerging, thanks to green chemistry-driven advances in enzyme engineering and immobilization and new chemical catalyst design. Such combinations could offer several advantages, especially by reducing time and yield losses associated with the isolation and purification of the reaction products, but also represent a big challenge since the optimal reaction conditions of bio- and chemical catalysis reactions are often different. This mini-review gives an overview of bio- and inorganic catalysts having the potential to be used in combination for lignin depolymerization. We also discuss key aspects to consider when combining these catalysts in one-pot reactions.
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