Voltage stabilizer and nanofiller in enhancement of insulation properties of cross‐linked polyethylene

This paper investigates the influence of voltage stabilizer and nanofiller addition on the insulation performance of the cross-linked polyethylene (XLPE). The test samples of XLPE/stabilizer blends consisting of 1 wt% m-aminobenzoic acid, XLPE nanocomposites consisting of 0.5 wt% nano MgO and XLPE hybrid composite consisting of both voltage stabilizer and nanofillers were prepared. Various physicochemical and electrical properties were measured to analyze the performance of prepared samples. The obtained results show that the addition of nanofillers deteriorates the electrical insulation performance of the XLPE. On the other hand, the voltage stabilizer addition proves to be suitable for enhancing the electrical insulation performance of the XLPE. Meanwhile, the hybrid XLPE composites have shown medium behavior. The voltage stabilizer addition reduces, but the nanofillers increase the space charge density inside the XLPE compared to pure XLPE. It is also found that the dispersion of the voltage stabilizer in the material is uniform, whereas the nanofillers are aggregated. Furthermore, both additives slightly improve the thermal stability of the XLPE. The trap level theory based on quantum chemical calculation is proposed to explain the influence mechanism of the additives on the XLPE.