催化作用
铈
锰
化学
ZSM-5型
选择性催化还原
无机化学
氧化还原
化学工程
沸石
有机化学
工程类
作者
Jiawei Ji,Yu Tang,Lixin Han,Pan Ran,Song Wang,Yi Cai,Wei Tan,Jingfang Sun,Changjin Tang,Lin Dong
标识
DOI:10.1016/j.cej.2022.136530
摘要
The application of cerium-manganese oxides (CeMn) in controlling exhaust gas from biomass combustion is greatly inhibited due to poor resistance to alkali metals. Herein, we report a smart strategy to circumvent the K poisoning problem of CeMn by physically coupling with ZSM-5, which exhibited almost no activity loss even under a high loading of 2 wt% K2O. Results showed that in contrast to the conventionally believed disturbance of redox property and reduction of acid sites, the dominant effect from K loading on the deactivation of CeMn catalysts lies on the formation of chemically inert nitrates, which significantly restrains the reaction cycle via Langmuir-Hinshelwood route. With ZSM-5 hybridization, the stable nitrates over CeMn can be facilely activated and consumed by NH4+ species introduced by ZSM-5, thus transforming poisoning sites into active sites and ensuring superior catalytic performance. The study presenting here not only provides an efficient strategy for fabricating NH3-SCR catalysts with superior K resistance but also sheds new light on the deactivation mechanism of K over CeMn catalysts.
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