化学
裂解酶
膦酸盐
碳纤维
糖基
水解
细菌
立体化学
基质(水族馆)
酶
生物化学
有机化学
材料科学
海洋学
生物
复合数
复合材料
遗传学
地质学
作者
Yanhua Luo,David L. Zechel
摘要
Carbonphosphorous lyase is a multienzyme system found in many species of bacteria that is distinguished by its ability to hydrolyze a broad array of unactivated alkylphosphonates. α-D-Ribofuranosyl alkylphosphonates are potential metabolic intermediates generated by the carbonphosphorous lyase pathway. Here we describe a facile synthesis of α-D-ribofuranosyl alkylphosphonates using β-D-ribofuranosyl trichloracetimidate as a glycosyl donor.Key words: carbonphosphorous lyase, phn operon, phnN, phosphonates, glycosyl trichloroacetimidate donor, α-D-ribofuranosyl ethylphosphonate.
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