化学
电催化剂
双功能
双金属片
钴
锰
无机化学
析氧
氧气
金属
氧化锰
多孔性
氧化物
催化作用
电化学
电极
有机化学
物理化学
作者
Gulnara Yusibova,Jürgen-Martin Assafrei,Kefeng Ping,Jaan Aruväli,Päärn Paiste,Maike Käärik,Jaan Leis,Helle‐Mai Piirsoo,Aile Tamm,Arvo Kikas,Vambola Kisand,Pavel Starkov,Nadežda Kongi
标识
DOI:10.1016/j.jelechem.2023.117161
摘要
This work reports a novel ligand-enabled strategy to incorporate dual metals into metal–organic-framework-derived bifunctional oxygen electrocatalysts. The involvement of bimetallic systems helps to reduce the necessity for critical raw materials while enhancing the overall electroactivity of the catalyst. Herein, we introduce a unique mixed-metal manganese/cobalt metal–organic framework (TAL-42) as a versatile single precursor for the facile preparation of highly efficient bifunctional oxygen electrocatalysts. Rotating disk electrode (RDE) experiments in 0.1 M KOH demonstrated that forming the heterogeneous bimetallic surface with metal-Nx functionalities results in an excellent bifunctional performance toward oxygen reduction/evolution reaction. The TAL-42–900 material exhibited superior bifunctional ORR/OER performance (ΔE = 0.80 V) to commercial Pt/C + RuO2 catalyst (ΔE = 0.84 V). In a rechargeable zinc-air battery test, the TAL-42–900 air cathode possessed excellent efficiency with a maximum power density of 155 mW cm−2 without degradation over prolonged cycling.
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