Advances in flexible ionic thermal sensors: present and perspectives

Ionic thermal sensors (ITSs) represent a promising frontier in sensing technology, offering unique advantages over conventional electronic sensors. Comprising a polymer matrix and electrolyte, these sensors possess inherent flexibility, stretchability, and biocompatibility, allowing them to establish stable and intimate contact with soft surfaces without inducing mechanical or thermal stress. Through an ion migration/dissociation mechanism similar to biosensing, ITSs ensure low impedance contact and high sensitivity, especially in physiological monitoring applications. This review provides a comprehensive overview of ionic thermal sensing mechanisms, contrasting them with their electronic counterparts. Additionally, it explores the intricacy of the sensor architecture, detailing the roles of active sensing elements, stretchable electrodes, and flexible substrates. The decoupled sensing mechanisms for skin-inspired multimodal sensors are also introduced based on several representative examples. The latest applications of ITS are categorized into ionic skin (i-skin), healthcare, spatial thermal perception, and environment detection, regarding their materials, structures, and operation modes. Finally, the perspectives of ITS research are presented, emphasizing the significance of standardized sensing parameters and emerging requirements for practical applications.