Advanced Alkali Metal Batteries Based on MOFs and Their Composites

Abstract The integration of metal‐organic frameworks (MOFs) with functional materials has established a versatile platform for a wide range of energy storage applications. Due to their large specific surface area, high porosity, and tunable structural properties, MOFs hold significant promise as components in energy storage systems, including electrodes, electrolytes, and separators for alkali metal‐ion batteries (AIBs). Although lithium‐ion batteries (LIBs) are widely used, their commercial graphite anode materials are nearing their theoretical capacity limits, and the scarcity of lithium and cobalt resources increases costs. Although zinc‐ion batteries (ZIBs) suffer from limited cycling stability, they are attractive for their low cost, high capacity, and excellent safety. Meanwhile, potassium‐ion (PIBs) and sodium‐ion batteries (SIBs) show promise due to their affordability and abundant resources, but they encounter issues such as short cycle life and low energy density. This review outlines the applications of MOF composites in LIBs, SIBs, and ZIBs, introduces common synthesis methods, and forecasts future development directions and challenges in energy storage applications. We emphasize how the understanding can lay the foundation for developing MOF composites with enhanced functionalities.